Debut of the First Practical 'Artificial Leaf'

"A practical artificial leaf has been one of the Holy Grails of science for decades," said Daniel Nocera, Ph.D., who led the research team."We believe we have done it. The artificial leaf shows particular promise as an inexpensive source of electricity for homes of the poor in developing countries. Our goal is to make each home its own power station," he said."One can envision villages in India and Africa not long from now purchasing an affordable basic power system based on this technology."

The device bears no resemblance to Mother Nature's counterparts on oaks, maples and other green plants, which scientists have used as the model for their efforts to develop this new genre of solar cells. About the shape of a poker card but thinner, the device is fashioned from silicon, electronics and catalysts, substances that accelerate chemical reactions that otherwise would not occur, or would run slowly. Placed in a single gallon of water in a bright sunlight, the device could produce enough electricity to supply a house in a developing country with electricity for a day, Nocera said. It does so by splitting water into its two components, hydrogen and oxygen.

The hydrogen and oxygen gases would be stored in a fuel cell, which uses those two materials to produce electricity, located either on top of the house or beside it.

Nocera, who is with the Massachusetts Institute of Technology, points out that the"artificial leaf" is not a new concept. The first artificial leaf was developed more than a decade ago by John Turner of the U.S. National Renewable Energy Laboratory in Boulder, Colorado. Although highly efficient at carrying out photosynthesis, Turner's device was impractical for wider use, as it was composed of rare, expensive metals and was highly unstable -- with a lifespan of barely one day.

Nocera's new leaf overcomes these problems. It is made of inexpensive materials that are widely available, works under simple conditions and is highly stable. In laboratory studies, he showed that an artificial leaf prototype could operate continuously for at least 45 hours without a drop in activity.

The key to this breakthrough is Nocera's recent discovery of several powerful new, inexpensive catalysts, made of nickel and cobalt, that are capable of efficiently splitting water into its two components, hydrogen and oxygen, under simple conditions. Right now, Nocera's leaf is about 10 times more efficient at carrying out photosynthesis than a natural leaf. However, he is optimistic that he can boost the efficiency of the artificial leaf much higher in the future.

"Nature is powered by photosynthesis, and I think that the future world will be powered by photosynthesis as well in the form of this artificial leaf," said Nocera, a chemist at Massachusetts Institute of Technology in Cambridge, Mass.

Nocera acknowledges funding from The National Science Foundation and Chesonis Family Foundation.

Source

Smaller Particles Could Make Solar Panels More Efficient

The results are published in the April issue of the journalACS Nano.

The advance provides evidence to support a controversial idea, called multiple-exciton generation (MEG), which theorizes that it is possible for an electron that has absorbed light energy, called an exciton, to transfer that energy to more than one electron, resulting in more electricity from the same amount of absorbed light.

Quantum dots are human-made atoms that confine electrons to a small space. They have atomic-like behavior that results in unusual electronic properties on a nanoscale. These unique properties may be particularly valuable in tailoring the way light interacts with matter.

Experimental verification of the link between MEG and quantum dot size is a hot topic due to a large degree of variation in previously published studies. The ability to generate an electrical current following MEG is now receiving a great deal of attention because this will be a necessary component of any commercial realization of MEG.

For this study, Lusk and collaborators used a National Science Foundation (NSF)-supported high performance computer cluster to quantify the relationship between the rate of MEG and quantum dot size.

They found that each dot has a slice of the solar spectrum for which it is best suited to perform MEG and that smaller dots carry out MEG for their slice more efficiently than larger dots. This implies that solar cells made of quantum dots specifically tuned to the solar spectrum would be much more efficient than solar cells made of material that is not fabricated with quantum dots.

According to Lusk,"We can now design nanostructured materials that generate more than one exciton from a single photon of light, putting to good use a large portion of the energy that would otherwise just heat up a solar cell."

The research team, which includes participation from the National Renewable Energy Laboratory, is part of the NSF-funded Renewable Energy Materials Research Science and Engineering Center at the Colorado School of Mines in Golden, Colo. The center focuses on materials and innovations that will significantly impact renewable energy technologies. Harnessing the unique properties of nanostructured materials to enhance the performance of solar panels is an area of particular interest to the center.

"These results are exciting because they go far towards resolving a long-standing debate within the field," said Mary Galvin, a program director for the Division of Materials Research at NSF."Equally important, they will contribute to establishment of new design techniques that can be used to make more efficient solar cells."

Source

Neutron Analysis Yields Insight Into Bacteria for Solar Energy

Researchers from Washington University in St. Louis and the Department of Energy's Oak Ridge National Laboratory used small-angle neutron scattering to analyze the structure of chlorosomes in green photosynthetic bacteria. Chlorosomes are efficient at collecting sunlight for conversion to energy, even in low-light and extreme environments.

"It's one of the most efficient light harvesting antenna complexes found in nature," said co-author and research scientist Volker Urban of ORNL's Center for Structural Molecular Biology, or CSMB.

Neutron analysis performed at the CSMB's Bio-SANS instrument at the High Flux Isotope Reactor allowed the team to examine chlorosome structure under a range of thermal and ionic conditions.

"We found that their structure changed very little under all these conditions, which shows them to be very stable," Urban said."This is important for potential biohybrid applications -- if you wanted to use them to harvest light in synthetic materials like a hybrid solar cell, for example."

The size, shape and organization of light-harvesting complexes such as chlorosomes are critical factors in electron transfer to semiconductor electrodes in solar devices. Understanding how chlorosomes function in nature could help scientists mimic the chlorosome's efficiency to create robust biohybrid or bio-inspired solar cells.

"What's so amazing about the chlorosome is that this large and complicated assembly is able to capture light effectively across a large area and then funnel the light to the reaction center without losing it along the way," Urban said."Why this works so well in chlorosomes is not well understood at all."

"We're trying to find out general principles that are important for capturing, harvesting and transporting light efficiently and see how nature has solved that," Urban said.

Small-angle neutron scattering enabled the team to clearly observe the complicated biological systems at a nanoscale level without damaging the samples.

"With neutrons, you have an advantage that you get a very sharp contrast between these two phases, the chlorosome and the deuterated buffer. This gives you something like a clear black and white image," Urban said.

The team, led by Robert Blankenship of Washington University, published its findings in the journalLangmuir. The research was supported through the Photosynthetic Antenna Research Center, an Energy Frontier Research Center funded by DOE's Office of Science. Both HFIR and the Bio-SANS facility at ORNL's Center for Structural Molecular Biology are also supported by DOE's Office of Science.

ORNL is managed by UT-Battelle for the Department of Energy's Office of Science.

Source

Testing Smart Energy Systems

In an innovative test laboratory, the SmartEnergyLab, they are investigating how to network various electrical household appliances and operate them remotely. In the residential housing sector in particular there is still a great deal of potential for smart energy-management systems that are capable of tailoring local power generation and consumption optimally to the power grid: What is the best time of day for utilizing solar power? How can we store the energy produced and possibly feed it back into the power grid at a lucrative price?

"Smart energy-systems technology for the consumer end of the distribution grid is the key to sustainable, secure energy supply," explains Christof Wittwer, group manager at Fraunhofer ISE. By mapping all the thermal and electrical energy flows, the lab constitutes a unique platform for analyzing, assessing and developing smart homes and smart grid solutions for the distribution grid."Basically, our lab is a simulator for potential energy systems for houses," says Wittwer.

The lab is equipped with renewable as well as electric and thermal producers and storage devices for tomorrow's single-family dwellings and apartment buildings. It boasts a stand-alone 5kW cogeneration plant, a two-cubic-meter buffer storage tank, a photovoltaic simulator, several PV inverters and various stand-alone inverters, a lithium-ion battery pack, a lead battery bank, a charging infrastructure for electric vehicles as well as other equipment. The combination of virtual and real components means researchers can simulate almost any energy system. For any given system they then assess and evaluate the potential energy savings for the customer associated with managing that system.

The service portfolio includes everything from"Integration assessment of thermal and electrical equipment in the system,""Function and communications testing for energy management systems" to the"Efficiency assessment of energy management and generation equipment." Energy suppliers and grid operators from across Germany are already leveraging the know-how of the Freiburg-based experts to determine the potential inherent in the decentralized management of this kind of equipment. Tariff models need to be assessed and their impact on the power grids investigated.

At the Hannover Messe from April 4 to 8, researchers on the joint Fraunhofer Energy Alliance will be showcasing a small yet very sophisticated device: The Smart Energy Gateway -- a component from the test lab -- organizes the way in which data is shared between energy supplier and consumer. The smart box networks the power meters for heat, water and electricity and ensures that the right control function is used to increase efficiency based on current consumption figures and tariff information. But the Gateway is not just a networked meter and energy management optimization device: It can also be used to control household appliances or heaters and to program on/off times. When should the heat pump, the washing machine or the dishwasher come on? In future, one worry you won't have when you're on vacation is whether you forgot to switch the stove off.

Source

Solar Power Systems Could Lighten the Load for British Soldiers

With the aim of being up to fifty per cent lighter than conventional chemical battery packs used by British infantry, the solar and thermoelectric-powered system could make an important contribution to future military operations.

The project is being developed by the University of Glasgow with Loughborough, Strathclyde, Leeds, Reading and Brunel Universities, with funding from the Engineering and Physical Sciences Research Council (EPSRC). It is also supported by the Defence Science and Technology Laboratory (Dstl).

The system's innovative combination of solar photovoltaic (PV) cells, thermoelectric devices and leading-edge energy storage technology will provide a reliable power supply round-the-clock, just like a normal battery pack. The team is also investigating ways of managing, storing and utilising heat produced by the system.

Because it is much lighter, the system will improve soldiers' mobility. Moreover, by eliminating the need to return to base regularly to recharge batteries, it will increase the potential range and duration of infantry operations. It will also absorb energy across the electromagnetic spectrum, making infantry less liable to detection by night vision equipment that uses infra-red technology, for instance.

Minister for Universities and Science David Willetts said:"The armed forces often need to carry around a huge amount of kit and the means to power it. It's great that specialists from a range of science disciplines are coming together to develop lighter, more reliable technology that will help to make life easier for them in the field."

Although substantial research into solar power for soldiers has already been conducted worldwide, this new UK project differs in its use of thermoelectric devices to complement solar cells, delivering genuine 24/7 power generation capability. The project team is also investigating how both types of device could actually be woven into soldiers' battle dress, which has never been done before.

During the day, the solar cells will produce electricity to power equipment. During the night, the thermoelectric devices will take over and perform the same function. The system will also incorporate advanced energy storage devices to ensure electricity is always available on a continuous basis.

"Infantry need electricity for weapons, radios, global positioning systems and many other vital pieces of equipment," says Professor Duncan Gregory of the University of Glasgow."Batteries can account for over ten per cent of the 45-70kg of equipment that infantry currently carry. By aiding efficiency and comfort, the new system could play a valuable role in ensuring the effectiveness of army operations."

PV cells, thermoelectric devices and advanced energy storage devices are already widely used in a range of applications. A key aim of the project team, however, is to produce robust, hard-wearing designs specifically for military use in tough, hostile conditions.

Because it will harness clean, free energy sources, the new power system will also offer significant environmental advantages compared with the conventional battery packs currently used by the British army.

To tackle the many challenges that the project presents, the team includes specialists from a wide range of disciplines including chemistry, materials science, process engineering, electrical engineering and design. Feedback from serving soldiers will also play a crucial role in optimising the power system for front-line use.

"We aim to produce a prototype system within two years," says Professor Gregory."We also anticipate that the technology that we develop could be adapted for other and very varied uses. One possibility is in niche space applications for powering satellites, another could be to provide means to transport medicines or supplies at cool temperatures in disaster areas or to supply fresh food in difficult economic or climatic conditions."

Source

Ultrafast Laser 'Scribing' Technique to Cut Cost, Hike Efficiency of Solar Cells

The innovation may help to overcome two major obstacles that hinder widespread adoption of solar cells: the need to reduce manufacturing costs and increase the efficiency of converting sunlight into an electric current, said Yung Shin, a professor of mechanical engineering and director of Purdue University's Center for Laser-Based Manufacturing.

Critical to both are tiny"microchannels" needed to interconnect a series of solar panels into an array capable of generating usable amounts of power, he said. Conventional"scribing" methods, which create the channels mechanically with a stylus, are slow and expensive and produce imperfect channels, impeding solar cells' performance.

"Production costs of solar cells have been greatly reduced by making them out of thin films instead of wafers, but it is difficult to create high-quality microchannels in these thin films," Shin said."The mechanical scribing methods in commercial use do not create high-quality, well-defined channels. Although laser scribing has been studied extensively, until now we haven't been able to precisely control lasers to accurately create the microchannels to the exacting specifications required."

The researchers hope to increase efficiency while cutting cost significantly using an"ultrashort pulse laser" to create the microchannels in thin-film solar cells, he said.

The work, funded with a three-year,$425,000 grant from the National Science Foundation, is led by Shin and Gary Cheng, an associate professor of industrial engineering. A research paper demonstrating the feasibility of the technique was published inProceedings of the 2011 NSF Engineering Research and Innovation Conferencein January. The paper was written by Shin, Cheng, and graduate students Wenqian Hu, Martin Yi Zhang and Seunghyun Lee.

"The efficiency of solar cells depends largely on how accurate your scribing of microchannels is," Shin said."If they are made as accurately as possibly, efficiency goes up."

Research results have shown that the fast-pulsing laser accurately formed microchannels with precise depths and sharp boundaries. The laser pulses last only a matter of picoseconds, or quadrillionths of a second. Because the pulses are so fleeting the laser does not cause heat damage to the thin film, removing material in precise patterns in a process called"cold ablation."

"It creates very clean microchannels on the surface of each layer," Shin said."You can do this at very high speed, meters per second, which is not possible with a mechanical scribe. This is very tricky because the laser must be precisely controlled so that it penetrates only one layer of the thin film at a time, and the layers are extremely thin. You can do that with this kind of laser because you have a very precise control of the depth, to about 10 to 20 nanometers."

Traditional solar cells are usually flat and rigid, but emerging thin-film solar cells are flexible, allowing them to be used as rooftop shingles and tiles, building facades, or the glazing for skylights. Thin-film solar cells account for about 20 percent of the photovoltaic market globally in terms of watts generated and are expected to account for 31 percent by 2013.

The researchers plan to establish the scientific basis for the laser-ablation technique by the end of the three-year period. The work is funded through NSF's Civil Mechanical and Manufacturing Innovation division.

Information about photovoltaic cells is available from the U.S. Department of Energy's National Renewable Energy Laboratory athttp://www.nrel.gov/learning/re_photovoltaics.html

Source